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R404A is a HFC (Hydrofluorocarbon) refrigerant blend designed to replace R502 and R22 in low and medium-temperature commercial refrigeration applications. It is a near-azeotropic mixture consisting of R125 (44%)R143a (52%), and R134a (4%).

General Characteristics

  • Environmental Profile: It has an Ozone Depletion Potential (ODP) of 0. However, it has a very high Global Warming Potential (GWP) of 3922, which makes it a primary target for phase-out regulations (like the EU F-Gas Regulation).
  • Safety Classification: Rated as A1 (Non-flammable and non-toxic) by ASHRAE.
  • Temperature Glide: Although it is a blend, its temperature glide is very low (less than 0.5 K), making it behave almost like a single-component gas.
  • Lubrication: It is not compatible with mineral oils. It must be used with POE (Polyolester) synthetic lubricants.
  • Performance: Known for its high cooling capacity and reliability in extreme low-temperature conditions.

Technical Specifications

PropertyValue
ComponentsR125 / R143a / R134a
Molecular Weight97.6 g/mol
Boiling Point (at 1 atm)-46.5 °C (-51.7 °F)
Critical Temperature72.1 °C (161.8 °F)
Critical Pressure37.3 bar (540.9 psia)
Liquid Density (at 25°C)1044 kg/m³
Vapor Pressure (at 25°C)12.6 bar (182.7 psia)
Safety GroupA1

Typical Applications

  • Commercial Refrigeration: Supermarket display cases, walk-in freezers, and reach-in coolers.
  • Industrial Cooling: Food processing plants and cold storage warehouses.
  • Transport Refrigeration: Refrigerated trucks, trailers, and marine shipping containers.